Strategies to Increase Nitrogen Pickup Using Ferrochromium Nitride

Release Time:

2026-09-11 17:22

1. Selection and Feeding Method of Ferrochromium Nitride

  • Increase the addition rate of ferrochromium nitride: Calculate the nitrogen mass balance and moderately raise the ferrochromium nitride dosage. The concurrent rise in chromium content and its impact on molten steel composition must be taken into consideration.
  • Adopt high-nitrogen grade ferrochromium nitride: Select grades with higher nitrogen content (e.g., ferrochromium nitride containing 6–8% N) to minimise dilution of molten steel by impurity elements.
  • Batch feeding: Prevent nitrogen escape caused by one-time bulk addition. Add the alloy in 2 to 3 batches after complete melting, with an interval of 5–10 minutes between each addition to boost nitrogen absorption efficiency.

2. Melting Process Optimisation

  • Control melting temperature: Nitrogen solubility in molten steel rises as temperature drops. Reduce tapping temperature appropriately (e.g., 1500–1550°C) while guaranteeing adequate fluidity of molten steel.
  • Pressurised melting: If equipment conditions permit, introduce nitrogen gas and maintain pressure at 0.1–0.3 MPa to greatly improve nitrogen solubility. (Approx. 0.01–0.02% N gain per 0.1 MPa pressure increase.)
  • Electromagnetic stirring: Enhance flow within the molten pool to accelerate dissolution of ferrochromium nitride and achieve uniform nitrogen distribution.

3. Synergistic Control of Alloying Elements

  • Adjust Cr and Mn contents: Chromium and manganese are nitrogen-stabilising elements. Raising Cr to 17–18% and Mn to 8–10% can improve nitrogen solubility.
  • Control carbon and sulphur levels: Maintain low carbon (<0.03%) and low sulphur (<0.01%) to mitigate nitrogen loss via gaseous compounds formed with carbon and sulphur.

4. Measures to Suppress Nitrogen Escape

  • Slag covering protection: Cover molten steel with basic slag in the later melting stage to isolate nitrogen from air contact.
  • Shorten operation duration: Reduce holding time at high temperatures and complete tapping and pouring rapidly.

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