Strategies to Increase Nitrogen Pickup Using Ferrochromium Nitride
Release Time:
2026-09-11 17:22
1. Selection and Feeding Method of Ferrochromium Nitride
- Increase the addition rate of ferrochromium nitride: Calculate the nitrogen mass balance and moderately raise the ferrochromium nitride dosage. The concurrent rise in chromium content and its impact on molten steel composition must be taken into consideration.
- Adopt high-nitrogen grade ferrochromium nitride: Select grades with higher nitrogen content (e.g., ferrochromium nitride containing 6–8% N) to minimise dilution of molten steel by impurity elements.
- Batch feeding: Prevent nitrogen escape caused by one-time bulk addition. Add the alloy in 2 to 3 batches after complete melting, with an interval of 5–10 minutes between each addition to boost nitrogen absorption efficiency.
2. Melting Process Optimisation
- Control melting temperature: Nitrogen solubility in molten steel rises as temperature drops. Reduce tapping temperature appropriately (e.g., 1500–1550°C) while guaranteeing adequate fluidity of molten steel.
- Pressurised melting: If equipment conditions permit, introduce nitrogen gas and maintain pressure at 0.1–0.3 MPa to greatly improve nitrogen solubility. (Approx. 0.01–0.02% N gain per 0.1 MPa pressure increase.)
- Electromagnetic stirring: Enhance flow within the molten pool to accelerate dissolution of ferrochromium nitride and achieve uniform nitrogen distribution.
3. Synergistic Control of Alloying Elements
- Adjust Cr and Mn contents: Chromium and manganese are nitrogen-stabilising elements. Raising Cr to 17–18% and Mn to 8–10% can improve nitrogen solubility.
- Control carbon and sulphur levels: Maintain low carbon (<0.03%) and low sulphur (<0.01%) to mitigate nitrogen loss via gaseous compounds formed with carbon and sulphur.
4. Measures to Suppress Nitrogen Escape
- Slag covering protection: Cover molten steel with basic slag in the later melting stage to isolate nitrogen from air contact.
- Shorten operation duration: Reduce holding time at high temperatures and complete tapping and pouring rapidly.
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